Dylan Edwards retains the fullback jersey ahead of James Tedesco, while Daley has shown faith in wingers Brian To'o and Zac Lomax, who have both played one match since returning from injury.
As a result, there was no room for Sea Eagles star Tom Trbojevic.
Latrell Mitchell and Stephen Crichton are the centres, as they were in last year's emphatic Origin II win at the MCG, while Cleary returns after missing the second and third match of the 2024 series through injury.
Moses was his replacement, and he will now play alongside the superstar playmaker at five-eighth.
[caption id="" align="aligncenter" width="560"]
Nathan Cleary will be partnered by Mitchell Moses in the halves for NSW in Origin I ©Grant Trouville/NRL Photos[/caption]
The forward pack of Yeo at lock, second-rowers Liam Martin and Angus Crichton, props Payne Haas and Mitchell Barnett, and hooker Reece Robson all played in Origin III as NSW regained the Shield.
Interchange prop Spencer Leniu and utility Connor Watson were also members of the winning Blues side, while second-rower Hudson Young returns after being dropped for the series decider.
Murray, Trbojevic and Bradman Best were all unavailable from the team that played in Origin III at Suncorp Stadium, while Luai was overlooked.
With injury concerns over Haas (quad) and Stephen Crichton (groin), Daley has named forwards Stefano Utoikamanu and Haumole Olakau’atu and centre Campbell Graham in an extended 20-man squad.
The Maroons team will be announced on Monday morning, but Canterbury officials have confirmed that veteran utility Kurt Mann, who plays as a middle forward for the Bulldogs, would be the club's second Origin debutant.
The Maroons have lost secondrower Tom Gilbert (pec muscle) and winger Murray Taulagi (calf), while fellow outside back Selwyn Cobbo is in doubt with a wrist injury.
WESTPAC NSW BLUES SQUAD
1. Dylan Edwards (Penrith Panthers)
2. Brian To’o (Penrith Panthers)
3. Stephen Crichton (Canterbury-Bankstown Bulldogs)
4. Latrell Mitchell (South Sydney Rabbitohs)
5. Zac Lomax (Parramatta Eels)
6. Mitchell Moses (Parramatta Eels)
7. Nathan Cleary (Penrith Panthers)
8. Mitchell Barnett (Warriors)
9. Reece Robson (North Queensland Cowboys)
10. Payne Haas (Brisbane Broncos)
11. Liam Martin (Penrith Panthers)
12. Angus Crichton (Sydney Roosters)
13. Isaah Yeo (c) (Penrith Panthers)
14. Connor Watson (Sydney Roosters)
15. Spencer Leniu (Sydney Roosters)
16. Hudson Young (Canberra Raiders)
17. Max King (Canterbury-Bankstown Bulldogs)
18. Campbell Graham (South Sydney Rabbitohs)
19. Stefano Utoikamanu (Melbourne Storm)
20. Haumole Olakau’atu (Manly Warringah Sea Eagles)
Source: NRL.com